Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2 N,P}palladium(II) dichloromethane hemisolvate
نویسندگان
چکیده
There are two independent Pd(II) complex mol-ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol-ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene ligand and two chloride anions.
منابع مشابه
Dichlorido{[2-(diphenylphosphino)phenyliminomethyl]ferrocene-κ2 N,P}platinum(II) dichloromethane hemisolvate
In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.
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